Search results for "Electronegativity equalization"

Complexes of organometallic compounds. LI. The correlation between 119Sn Mössbauer isomer shifts and partial atomic charges on tin in R3SnL compounds

1985

Abstract The 119Sn Mossbauer isomer shift parameters, δ, of compounds R3SnL (R = AlK, Ph; L = F, Cl, OH, OR′, CN, NCS, NCO, N3) have been correlated to partial atomic charges on tin QSn, calculated according to a valence state electronegativity equalization procedure carried out by the CHELEQ program. A unique δ/QSn correlation has been obtained for all the five-coordinated R3SnL species by using average δ parameters for the AlK3IV derivatives.